Enhancement of photostability in blue-light-emitting polymers doped with gold nanoparticles

被引：35

作者：

Park, JH

Lim, YT

Park, OO

Kim, YC

机构：

[1] Korea Adv Inst Sci & Technol, Ctr Adv Funct Polymers, Taejon 305701, South Korea

[2] Korea Adv Inst Sci & Technol, Dept Chem & Biomol Engn, Taejon 305701, South Korea

[3] Korea Inst Sci & Technol, Optoelect Mat Res Ctr, Seoul 130650, South Korea

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2003年 / 24卷 / 04期

关键词：

electroluminescence; nanoparticles; light-emitting diodes (LED); nanocomposites;

D O I：

10.1002/marc.200390051

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A dramatic increase in the photostability of a blue-light-emitting polymer, poly(9,9-dioctylfluorene), was achieved by the addition of 5-10 nm gold nanoparticles. The optical absorption band of the gold nanoparticles was tuned to resonate the triplet exciton ground state bandgap energy of the polymer. Photo-oxidation rate of poly(9,9-dioctylfluorene) was effectively reduced by doping the polymer with very small amounts (approximate to10(-6)-10(-5) volume fraction) of the gold nanoparticles.

引用

页码：331 / 334

页数：4

共 30 条

[1] Transient analysis of organic electrophosphorescence: I. Transient analysis of triplet energy transfer [J].