Carbon/carbon composite bipolar plate for proton exchange membrane fuel cells

被引:115
作者
Besmann, TM [1 ]
Klett, JW [1 ]
Henry, JJ [1 ]
Lara-Curzio, E [1 ]
机构
[1] Oak Ridge Natl Lab, Div Met & Ceram, Oak Ridge, TN 37830 USA
关键词
Proton exchange membrane fuel cells (PEMFC);
D O I
10.1149/1.1394023
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Carbon/carbon-composite bipolar plates for proton exchange membrane fuel cells (PEMFC) have been fabricated by slurry molding a chopped-fiber preform followed by sealing with chemically vapor-infiltrated carbon. The resulting component is hermetic with respect to through-thickness leakage and has a high electronic conductivity (200-300 S/cm) as a result of the deposited graphitic carbon. The material has a low density (0.96 g/cm(3)) due to retained porosity resulting in a low-weight component. Biaxial flexure strength was measured to be 175 +/- 26 MPa. Cell testing of a 100 cm(2) active area, single-sided plate indicated very low cell resistance and high efficiency, but with a somewhat steep drop-off in voltage with current at high values. Corrosion testing indicated minimal corrosion in fuel cell environments. (C) 2000 The Electrochemical Society. S0013-4651(99)09-074-6. All rights reserved.
引用
收藏
页码:4083 / 4086
页数:4
相关论文
共 9 条
[1]  
BAMMIDIPATI S, 1996, AICHE J, V42, P123
[2]   VAPOR-PHASE FABRICATION AND PROPERTIES OF CONTINUOUS-FILAMENT CERAMIC COMPOSITES [J].
BESMANN, TM ;
SHELDON, BW ;
LOWDEN, RA ;
STINTON, DP .
SCIENCE, 1991, 253 (5024) :1104-1109
[3]  
Borup RL, 1995, MATER RES SOC SYMP P, V393, P151, DOI 10.1557/PROC-393-151
[4]  
Delhaes P, 1997, P 14 INT C EUROCVD 1, P486
[5]  
Fuller T. F., 1997, Electrochemical Society Interface, V6, P26
[6]  
Ralph T.R., 1997, PLATIN MET REV, V41, P102
[7]   APPRAISAL OF BIAXIAL STRENGTH TESTING [J].
RITTER, JE ;
JAKUS, K ;
BATAKIS, A ;
BANDYOPADHYAY, N .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1980, 38-9 (MAY-) :419-424
[8]  
Vitman F.F., 1963, ZAVODSK LAB, V29, P863
[9]  
WEI GC, 1985, AM CERAM SOC BULL, V64, P691