Monolayer g-C3N4 Fluorescent Sensor for Sensitive and Selective Colorimetric Detection of Silver ion from Aqueous Samples

被引:68
作者
Cao, Yujuan [1 ,2 ]
Wu, Wei [1 ]
Wang, Song [1 ]
Peng, Hong [1 ]
Hu, Xiaogang [1 ,2 ]
Yu, Ying [1 ,2 ]
机构
[1] S China Normal Univ, Sch Chem & Environm, Guangzhou 510006, Guangdong, Peoples R China
[2] S China Normal Univ, Guangzhou Key Lab Analyt Chem Biomed, Guangzhou 510006, Guangdong, Peoples R China
基金
中国国家自然科学基金;
关键词
Monolayer g-C3N4; Fluorescent sensor; Silver (I) ion; Aqueous samples; GRAPHITIC CARBON(IV) NITRIDE; METAL-IONS; NANOPARTICLES; PRECONCENTRATION; COMPOSITE; GRAPHENE; GOLD;
D O I
10.1007/s10895-016-1764-9
中图分类号
Q5 [生物化学];
学科分类号
070307 [化学生物学];
摘要
Rapid and sensitive detection of heavy-metal ions in natural water environments worldwide is urgently needed because of their severe threats to human health. In the present work, monolayer graphite-like flake C3N4 (g-C3N4) materials were applied as a new fluorescent sensor for the detection of trace silver ion in aqueous solution. The thickness of synthesized g-C3N4 was 0.45 nm and obtained by exfoliating twice with ultrasonic. With the presence of ethylene diamine tetraacetic acid as a screening agent, the highly sensitive sensor reached a low detection limit of 52.3 nmol/L for silver (I) ion and there was no disturbance when silver (I) ion coexisted with other metal ions in water samples. Under the optimal conditions, the monolayer g-C3N4 was successfully used to detect trace silver (I) ion in different environmental water and drinking water samples.
引用
收藏
页码:739 / 744
页数:6
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