Crystallized water: Internal and external ice fragments in polycyclic hosts

被引:33
作者
Kang, Sung Ok [1 ]
Powell, Douglas [1 ]
Day, Victor W. [1 ]
Bowman-James, Kristin [1 ]
机构
[1] Univ Kansas, Dept Chem, Lawrence, KS 66045 USA
关键词
D O I
10.1021/cg0608817
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Two crystal structures of cyclic water hexamers are reported, one with a bicyclic cryptand and the other with a tricyclic host. In the bicycle structure, the water molecules lie between the cryptands. In the tricycle structure, the hexameric water cluster is almost totally encapsulated within the host framework.
引用
收藏
页码:606 / 608
页数:3
相关论文
共 48 条
[1]   A well-resolved ice-like (H2O)8 cluster in an organic supramolecular complex [J].
Atwood, JL ;
Barbour, LJ ;
Ness, TJ ;
Raston, CL ;
Raston, PL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (29) :7192-7193
[2]   Characterization of a well resolved supramolecular ice-like (H2O)10 cluster in the solid state [J].
Barbour, LJ ;
Orr, GW ;
Atwood, JL .
CHEMICAL COMMUNICATIONS, 2000, (10) :859-860
[3]   An intermolecular (H2O)10 cluster in a solid-state supramolecular complex [J].
Barbour, LJ ;
Orr, GW ;
Atwood, JL .
NATURE, 1998, 393 (6686) :671-673
[4]   Synthesis and crystallographic characterization of an octameric water complex, (H2O)8 [J].
Blanton, WB ;
Gordon-Wylie, SW ;
Clark, GR ;
Jordan, KD ;
Wood, JT ;
Geiser, U ;
Collins, TJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (14) :3551-3552
[5]  
Custelcean R, 2000, ANGEW CHEM INT EDIT, V39, P3094, DOI 10.1002/1521-3773(20000901)39:17<3094::AID-ANIE3094>3.0.CO
[6]  
2-P
[7]   Novel water clusters in the crystalline state: structures of a symmetrical, cyclic hexamer and an 'opened-cube' octamer [J].
Doedens, RJ ;
Yohannes, E ;
Khan, MI .
CHEMICAL COMMUNICATIONS, 2002, (01) :62-63
[8]   Distinct dynamic behaviors of water molecules in hydrated pores [J].
Febles, Martin ;
Perez-Hernandez, Natalia ;
Perez, Cirilo ;
Rodriguez, Matias L. ;
Foces-Foces, Concepcion ;
Roux, Maria Victoria ;
Morales, Ezequiel Q. ;
Buntkowsky, Gerd ;
Limbach, Hans-Heinrich ;
Martin, Julio D. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (31) :10008-10009
[9]   COMPLETE ENERGY PROFILE OF A CHIRAL PROPELLER COMPOUND - TRIS-(2'-METHYLBENZIMIDAZOL-1'-YL)METHANE (TMBM) - CHROMATOGRAPHIC RESOLUTION ON TRIACETYL CELLULOSE, X-RAY STRUCTURES OF THE RACEMIC AND ONE ENANTIOMER, AND DYNAMIC NMR-STUDY [J].
FOCESFOCES, C ;
CANO, FH ;
MARTINEZRIPOLL, M ;
FAURE, R ;
ROUSSEL, C ;
CLARAMUNT, RM ;
LOPEZ, C ;
SANZ, D ;
ELGUERO, J .
TETRAHEDRON-ASYMMETRY, 1990, 1 (02) :65-86
[10]   Structure of a discrete hexadecameric water cluster in a metal-organic framework structure [J].
Ghosh, SK ;
Bharadwaj, PK .
INORGANIC CHEMISTRY, 2004, 43 (22) :6887-6889