Rhodium-catalyzed Si-F exchange reaction between fluorobenzenes and a disilane. Catalytic reaction involving cleavage of C-F bonds

被引：100

作者：

Ishii, Y ^{[1
]}

Chatani, N ^{[1
]}

Yorimitsu, S ^{[1
]}

Murai, S ^{[1
]}

机构：

[1] Osaka Univ, Fac Engn, Dept Appl Chem, Osaka 565, Japan

来源：

CHEMISTRY LETTERS | 1998年 / 02期

关键词：

D O I：

10.1246/cl.1998.157

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of functionalized fluorobenzenes, such as fluoroacetophenones and (fluorophenyl) oxazolines, with Me3SiSiMe3 in the presence of a catalytic amount of a rhodium complex results in a site-selective Si-F exchange to give ortho(trimethylsilyl)fluorobenzenes. The reaction involves cleavage of C-F bonds.

引用

页码：157 / 158

页数：2

共 15 条

[1] HOMOGENEOUS METAL-CATALYZED HYDROGENOLYSIS OF C-F BONDS
AIZENBERG, M
MILSTEIN, D
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (33) : 8674 - 8675
[2] CATALYTIC ACTIVATION OF CARBON-FLUORINE BONDS BY A SOLUBLE TRANSITION-METAL COMPLEX
AIZENBERG, M
MILSTEIN, D
[J]. SCIENCE, 1994, 265 (5170) : 359 - 361
[3] Photoinduced catalytic defluorination of perfluoroalkanes to give perfluoroalkenes
Burdeniuc, J
Crabtree, RH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (10) : 2525 - 2526
[4] Ru-3(CO)(12)-catalyzed reaction of pyridylbenzenes with carbon monoxide and olefins. Carbonylation at a C-H bond in the benzene ring
Chatani, N
Ie, Y
Kakiuchi, F
Murai, S
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (08) : 2604 - 2610
[5] REGIOSPECIFIC REPLACEMENT OF FLUORINE BY HYDROGEN IN AN AROMATIC RING INDUCED BY A RARE-EARTH ORGANOMETALLIC
DEACON, GB
FORSYTH, CM
SUN, JH
[J]. TETRAHEDRON LETTERS, 1994, 35 (07) : 1095 - 1098
[6] Mechanism of carbon-fluorine bond activation by (C5Me5)Rh(PMe3)H-2
Edelbach, BL
Jones, WD
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (33) : 7734 - 7742
[7] TRANSFORMATIONS OF CHLOROARENES, CATALYZED BY TRANSITION-METAL COMPLEXES
GRUSHIN, VV
ALPER, H
[J]. CHEMICAL REVIEWS, 1994, 94 (04) : 1047 - 1062
[8] PALLADIUM-MEDIATED SILYLATION OF ORGANIC HALIDES WITH DISILANE/F- REAGENT
HATANAKA, Y
HIYAMA, T
[J]. TETRAHEDRON LETTERS, 1987, 28 (40) : 4715 - 4718
[9] ACTIVATION OF CARBON FLUORINE BONDS BY METAL-COMPLEXES
KIPLINGER, JL
RICHMOND, TG
OSTERBERG, CE
[J]. CHEMICAL REVIEWS, 1994, 94 (02) : 373 - 431
[10] Group IV metallocene-mediated synthesis of fluoroaromatics via selective defluorination of saturated perfluorocarbons
Kiplinger, JL
Richmond, TG
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (07) : 1805 - 1806

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