Carbon rings and cages in the growth of single-walled carbon nanotubes

被引:36
作者
Kiang, CH [1 ]
机构
[1] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA
关键词
D O I
10.1063/1.1287850
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We present a growth model for single-walled carbon nanotubes (SWNTs) based on experimental observation and energetic considerations. Carbon rings, observed experimentally and suggested to be fullerene precursors, are the templates for SWNTs nucleation. SWNTs grow by addition of C-2 radicals to catalytically induced reactive sites. This model is consistent with known experimental results and explains the characteristic diameter distribution of SWNTs as resulting from the gas-phase distribution of carbon ring isomers. (C) 2000 American Institute of Physics. [S0021-9606(00)71333-X].
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页码:4763 / 4766
页数:4
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