Photocatalytic WO3/TiO2 nanoparticles working under visible light

被引:91
作者
Chai, Seung Yong [1 ]
Kim, Yong Joo [1 ]
Lee, Wan In [1 ]
机构
[1] Inha Univ, Dept Chem, Inchon 402751, South Korea
关键词
nanoparticle; visible light; photocatalyst; WO3/TiO2; TiO2;
D O I
10.1007/s10832-006-9073-3
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
WO3/TiO2 was prepared by modifying the surface of TiO2 with clusters of crystallized WO3. Previously, we have reported that the TiO2 covered with the monolayer of WO3 shows greatly enhanced photocatalytic activity under UV light in decomposing VOCs. Here we report that the WO3/TiO2 can also be activated by visible light in the photocatalytic decomposition of gaseous 2-propanol. The structure of WO3/TiO2 was examined by X-ray diffraction (XRD), TEM, UV-Visible and Raman spectra. The samples with 10 mol% of WO3 annealed at 700 degrees C provide the optimum photocatalytic efficiency in visible range. We also suggest the mechanism for the WO3/TiO2 working under visible light.
引用
收藏
页码:909 / 912
页数:4
相关论文
共 14 条
[1]   The design and development of highly reactive titanium oxide photocatalysts operating under visible light irradiation [J].
Anpo, M ;
Takeuchi, M .
JOURNAL OF CATALYSIS, 2003, 216 (1-2) :505-516
[2]   Nanosize Ti-W mixed oxides:: Effect of doping level in the photocatalytic degradation of toluene using sunlight-type excitation [J].
Fuerte, A ;
Hernández-Alonso, MD ;
Maira, AJ ;
Martínez-Arias, A ;
Fernández-García, M ;
Conesa, JC ;
Soria, J ;
Munuera, G .
JOURNAL OF CATALYSIS, 2002, 212 (01) :1-9
[3]   ENVIRONMENTAL APPLICATIONS OF SEMICONDUCTOR PHOTOCATALYSIS [J].
HOFFMANN, MR ;
MARTIN, ST ;
CHOI, WY ;
BAHNEMANN, DW .
CHEMICAL REVIEWS, 1995, 95 (01) :69-96
[4]  
Kwon YT, 2000, J CATAL, V191, P192
[5]   Photocatalytic activity of WOx-TiO2 under visible light irradiation [J].
Li, XZ ;
Li, FB ;
Yang, CL ;
Ge, WK .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2001, 141 (2-3) :209-217
[6]   Photocatalysis and photoinduced hydrophilicity of various metal oxide thin films [J].
Miyauchi, M ;
Nakajima, A ;
Watanabe, T ;
Hashimoto, K .
CHEMISTRY OF MATERIALS, 2002, 14 (06) :2812-2816
[7]   PHOTOELECTROCHEMISTRY - APPLICATIONS TO SOLAR-ENERGY CONVERSION [J].
NOZIK, AJ .
ANNUAL REVIEW OF PHYSICAL CHEMISTRY, 1978, 29 :189-222
[8]   Preparation of transparent particulate MoO3/TiO2 and WO3/TiO2 films and their photocatalytic properties [J].
Song, KY ;
Park, MK ;
Kwon, YT ;
Lee, HW ;
Chung, WJ ;
Lee, WI .
CHEMISTRY OF MATERIALS, 2001, 13 (07) :2349-2355
[9]   Photocatalytic properties of TiO2/WO3 bilayers deposited by reactive sputtering [J].
Takahashi, T ;
Nakabayashi, H ;
Yamada, N ;
Tanabe, J .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A, 2003, 21 (04) :1409-1413
[10]   PHOTOCATALYTIC DEGRADATION OF ORGANIC-WATER CONTAMINANTS - MECHANISMS INVOLVING HYDROXYL RADICAL ATTACK [J].
TURCHI, CS ;
OLLIS, DF .
JOURNAL OF CATALYSIS, 1990, 122 (01) :178-192