Oligothiophenes for pattern formation by stamping

被引：8

作者：

Allard, S ^{[1
]}

Braun, L ^{[1
]}

Brehmer, M ^{[1
]}

Zentel, R ^{[1
]}

机构：

[1] Univ Mainz, Inst Organ Chem, D-55099 Mainz, Germany

来源：

MACROMOLECULAR CHEMISTRY AND PHYSICS | 2003年 / 204卷 / 01期

关键词：

microstructure; moulding; organic semiconductors; photopolymerization; soft lithography;

D O I：

10.1002/macp.200290056

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Oligothiophene monomers with a fixed length varying from 3 to 5 thiophene rings were prepared by Stille coupling. They were functionalised with one or two methacrylate groups to allow polymerization and cross-linking. These monomers can be patterned with the help of soft silicon stamps (e.g., with the micro-injection moulding in capillaries process) on substrates like glass or flexible polymer foils. If a photoinitiator has been added, they can then be hardened by exposure to UV-light through the transparent stamp. Afterwards the stamp can be removed. This allows the preparation of several centimeters long oligothiophene lines of a width varying between 50 and 0.5 mum. These lines of semiconducting organic material can be used e.g., as an orientation layer for liquid crystals.

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收藏

页码：68 / 75

页数：8

相关论文

共 24 条

[11] Chemical amplification resists: History and development within IBM [J].

Ito, H .

IBM JOURNAL OF RESEARCH AND DEVELOPMENT, 1997, 41 (1-2) :69-80

[12]

Kumada M, 1978, ORG SYNTH, V58, P127

[13] Ordering, graphoepitaxial orientation, and conformation of a polyfluorene derivative of the "hairy-rod" type on an oriented substrate of polyimide [J].

Lieser, G ;

Oda, M ;

Miteva, T ;

Meisel, A ;

Nothofer, HG ;

Scherf, U ;

Neher, D .

MACROMOLECULES, 2000, 33 (12) :4490-4495

[14] ENHANCED ELECTRICAL-CONDUCTIVITY IN REGIOSELECTIVELY SYNTHESIZED POLY(3-ALKYLTHIOPHENES) [J].

MCCULLOUGH, RD ;

LOWE, RD .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (01) :70-72

[15] Printing meets lithography: Soft approaches to high-resolution printing [J].

Michel, B ;

Bernard, A ;

Bietsch, A ;

Delamarche, E ;

Geissler, M ;

Juncker, D ;

Kind, H ;

Renault, JP ;

Rothuizen, H ;

Schmid, H ;

Schmidt-Winkel, P ;

Stutz, R ;

Wolf, H .

IBM JOURNAL OF RESEARCH AND DEVELOPMENT, 2001, 45 (05) :697-719

[16] CHEMICAL AMPLIFICATION MECHANISMS FOR MICROLITHOGRAPHY [J].

REICHMANIS, E ;

HOULIHAN, FM ;

NALAMASU, O ;

NEENAN, TX .

CHEMISTRY OF MATERIALS, 1991, 3 (03) :394-407

[17] Poly(p-phenylene vinylene) copolymer patterns prepared via photolithographic techniques [J].

Renak, ML ;

Bazan, GC ;

Roitman, D .

SYNTHETIC METALS, 1998, 97 (01) :17-21

[18] Electroluminescence with organic compounds [J].

Salbeck, J .

BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1996, 100 (10) :1667-1677

[19] THE PALLADIUM-CATALYZED CROSS-COUPLING REACTIONS OF ORGANOTIN REAGENTS WITH ORGANIC ELECTROPHILES [J].

STILLE, JK .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1986, 25 (06) :508-523

[20] A CONVENIENT SYNTHESIS OF 2,5-THIENYLENE OLIGOMERS - SOME OF THEIR SPECTROSCOPIC AND ELECTROCHEMICAL PROPERTIES [J].

VANPHAM, C ;

BURKHARDT, A ;

SHABANA, R ;

CUNNINGHAM, DD ;

MARK, HB ;

ZIMMER, H .

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1989, 46 (3-4) :153-168