Characterization of semiflexible polyelectrolyte solutions in the presence of excess salt: From dilute to semidilute regime

被引：11

作者：

Buhler, E ^{[1
]}

Guetta, O ^{[1
]}

Rinaudo, M ^{[1
]}

机构：

[1] Univ Grenoble 1, CNRS, Ctr Rech Macromol Vegetales, F-38041 Grenoble, France

来源：

INTERNATIONAL JOURNAL OF POLYMER ANALYSIS AND CHARACTERIZATION | 2000年 / 6卷 / 1-2期

关键词：

polyelectrolyte; semiflexible chains; chitosan; static and dynamic light scattering; intrinsic viscosity;

D O I：

10.1080/10236660008034656

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Highly charged semiflexible polyelectrolyte chitosan was characterized in dilute and semidilute aqueous solutions in the presence of excess of salt by viscosity and static and dynamic light scattering. In the present paper, we report on the variation of the structural and dynamical parameters as a function of the ionic strength. Size of the polyions, virial coefficients and overlap concentration are parameters that are strongly influenced by excess salt concentration.

引用

页码：155 / 175

页数：21

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