Light-induced demixing of hole or electron transporting moieties

被引：11

作者：

Behl, M

Zentel, R ^{[1
]}

Broer, DJ

机构：

[1] Univ Mainz, Dept Organ Chem, D-55099 Mainz, Germany

[2] Philips Res Labs, NL-5656 AA Eindhoven, Netherlands

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2004年 / 25卷 / 20期

关键词：

conducting polymers; demixing; photopolymerization; triazine; triphenylamine;

D O I：

10.1002/marc.200400321

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

This paper describes the synthesis of two triphenylamine monomers (hole conducting) and one triazine monomer (electron conducting) which differ in their copolymerization parameters because of their styrene and vinyl ester nature. A blend of triphenylamine monomer and poly(ethylene glycol) and mixtures of both types of monomers (triphenylamine and triazine) were illuminated radicals, thus leading to lateral demixing. The experiments with mixtures of triphenylamine and triazine monomers show that the concentration of p- or n-type polymers can be modulated laterally in a controlled way.

引用

页码：1765 / 1770

页数：6

共 21 条

[1]

Behl M, 2002, ADV MATER, V14, P588, DOI 10.1002/1521-4095(20020418)14:8<588::AID-ADMA588>3.0.CO

[2]

2-K

[3]

Broer DJ, 1999, ADV MATER, V11, P573, DOI 10.1002/(SICI)1521-4095(199905)11:7<573::AID-ADMA573>3.0.CO

[4]

2-E