Effect of charge separation on the stability of large wavelength fluctuations during spinodal decomposition

被引：20

作者：

Bishop, CM ^{[1
]}

García, RE ^{[1
]}

Carter, WC ^{[1
]}

机构：

[1] MIT, Dept Mat Sci & Engn, Cambridge, MA 02139 USA

来源：

ACTA MATERIALIA | 2003年 / 51卷 / 06期

基金：

美国国家科学基金会;

关键词：

spinodal decomposition; stability; kinetics; DYNAMICS; FIELD; FILMS;

D O I：

10.1016/S1359-6454(02)00535-9

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A stability analysis of phase separation of charged species by spinodal decomposition is presented. The charge effects introduce a short wave number cutoff for linear perturbations about the homogeneous, neutral solution. Phase field calculations using a semi-implicit spectral method support this conclusion. This suggests that coarsening is limited in ionic solid systems that are unstable with respect to charged-phase separation. (C) 2003 Acta Materialia Inc. Published by Elsevier Science Ltd. All rights reserved.

引用

页码：1517 / 1524

页数：8

共 16 条

[1]

BADGER PH, 1967, EQUILIBRIUM THERMODY

[2] ON SPINODAL DECOMPOSITION [J].