Glass formation and glass structure of the BiO1.5-PbO-CuO system

被引：61

作者：

Hu, Y ^{[1
]}

Liu, NH ^{[1
]}

Lin, UL ^{[1
]}

机构：

[1] Tatung Inst Technol, Dept Mat Engn, Taipei 10451, Taiwan

来源：

JOURNAL OF MATERIALS SCIENCE | 1998年 / 33卷 / 01期

关键词：

D O I：

10.1023/A:1004382721435

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The glass-forming region of the BiO1.5-PbO-CuO system has been determined by the melt-quenching technique. The glass transition temperatures, T-g, and the first crystallization peak temperatures, T-x1, are around 240 degrees C and 285 degrees C, respectively. The glass structure consists of [BiO3] and [BiO6] units, and the conversion between these polyhedra mainly depends on the CuO and PbO content. The covalent characteristic in the infrared absorption spectra of the [PbOn] pyramidal units becomes significant when the glass contains more PbO.

引用

页码：229 / 234

页数：6

共 23 条

[1]

BISHOP WW, 1969, MEM GEOL SURV UGANDA, V10, P1

[2]

DIMITRIEV Y, 1992, B SOC ESP CERAMI VID, V3, P293

[3] GLASS-FORMATION IN BINARY-SYSTEMS WITH BI2O3 AND PBO PARTICIPATION [J].

DIMITRIEV, YB ;

MIHAILOVA, VT .

JOURNAL OF MATERIALS SCIENCE LETTERS, 1990, 9 (11) :1251-1254

[4] IR-SPECTRA AND STRUCTURE OF V2O5-GEO2-BI2O3 GLASSES [J].

DIMITROV, V ;

DIMITRIEV, Y ;

MONTENERO, A .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 1994, 180 (01) :51-57

[5]

DUMBAUGH WH, 1978, PHYS CHEM GLASSES, V19, P121

[6]

DUMBAUGH WH, 1986, PHYS CHEM GLASSES, V27, P119

[7] PREPARATION OF BI-SR-CA-CU-O SUPERCONDUCTORS FROM OXIDE-GLASS PRECURSORS [J].

HINKS, DG ;

SODERHOLM, L ;

CAPONE, DW ;

DABROWSKI, B ;

MITCHELL, AW ;

SHI, D .

APPLIED PHYSICS LETTERS, 1988, 53 (05) :423-425

[8] X-RAY-DIFFRACTION ANALYSIS ON THE STRUCTURE OF THE GLASSES IN THE SYSTEM PBO-SIO2 [J].

IMAOKA, M ;

HASEGAWA, H ;

YASUI, I .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 1986, 85 (03) :393-412

[9] PREPARATION OF HIGH-TC SUPERCONDUCTING BI-CA-SR-CU-O CERAMICS BY THE MELT QUENCHING METHOD [J].

KOMATSU, T ;

IMAI, K ;

SATO, R ;

MATUSITA, K ;

YAMASHITA, T .

JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS, 1988, 27 (04) :L533-L535

[10]

KONIJNENDIJK WL, 1976, PHILIPS RES LAB REPO, P227

← 1 2 3 →