Enantioselective hydrogenation of alpha,beta-unsaturated acids. Substrate-modifier interaction over cinchonidine modified Pd/Al2O3

被引：95

作者：

Borszeky, K ^{[1
]}

Mallat, T ^{[1
]}

Baiker, A ^{[1
]}

机构：

[1] ETH ZENTRUM, SWISS FED INST TECHNOL, DEPT CHEM ENGN & IND CHEM, CH-8092 ZURICH, SWITZERLAND

来源：

TETRAHEDRON-ASYMMETRY | 1997年 / 8卷 / 22期

关键词：

D O I：

10.1016/S0957-4166(97)00526-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

X-Ray diffraction, IR measurements and catalytic hydrogenation of various substituted acrylic acids in apolar solvents, as well as molecular modelling provide new insight into the nature of the cinchonidine-substrate interaction and a general rule to predict the major enantiomer. (C) 1997 Elsevier Science Ltd.

引用

页码：3745 / 3753

页数：9

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