Liquid-crystalline properties of alkyl 4-[2-(perfluorooctyl)ethoxy]benzoates

被引：46

作者：

Okamoto, H ^{[1
]}

Murai, H ^{[1
]}

Takenaka, S ^{[1
]}

机构：

[1] Yamaguchi Univ, Fac Engn, Dept Mat Sci & Engn, Yamaguchi 755, Japan

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1997年 / 70卷 / 12期

关键词：

D O I：

10.1246/bcsj.70.3163

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This paper describes the liquid-crystalline properties of alkyl 4-[2-(perfluorooctyl)ethoxy]benzoates (1) and bromo (2) and nitro (3) substituted compounds. For 1, the lower members show a smectic A phase; also the smectic A-isotropic transition temperatures and the latent heats decrease with increasing the carbon number of the hydrocarbon chain, An Xray examination indicated that the smectic A phase has an interdigited arrangement of molecules. The results are discussed in terms of inter-and intra-layer fluorophilic interactions around the perfluorooctyl groups.

引用

页码：3163 / 3166

页数：4

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