Carbon dioxide fixation by the cooperative effect of organotin and organotellurium oxides

被引：41

作者：

Beckmann, J ^{[1
]}

Dakternieks, D ^{[1
]}

Duthie, A ^{[1
]}

Lewcenko, NA ^{[1
]}

Mitchell, C ^{[1
]}

机构：

[1] Deakin Univ, Ctr Chiral & Mol Technol, Sch Biol & Chem Sci, Geelong, Vic 3217, Australia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 48期

关键词：

D O I：

10.1002/anie.200460155

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mypervalency and secondary bonding are the driving forces behind the rapid absorption of gaseous carbon dioxide by two organotellurium and organotin oxides and the unexpected formation of a unique tellurastannoxane cluster (see structure; dark red Te, black Sn, gray C, light red O). The absorption is reversible with the liberation of carbon dioxide being observed at temperatures between 90 and 145°C.

引用

页码：6683 / 6685

页数：3

共 26 条

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