The role of vaterite and aragonite in the formation of pseudo-biogenic carbonate structures: Implications for Martian exobiology

A simple synthesis of various forms of calcium carbonate with spherical and 'floral' morphologies is reported. Vaterite formation occurs at similar to 25 degrees C, aragonite at similar to 70 degrees C and calcite at about similar to 80 degrees C. These are produced when CO2 is reacted with an aqueous solution of calcium chloride in the presence of ammonia. These conditions may have existed at the surface of Mars in the past, leading us to conclude that such mineral formations may be common there. Although the initial phases are modified over time with changing temperature and pressure conditions, they still influence the final morphology of the carbonates observed. A comparison of these structures with those found in the Martian meteorite ALH84001 suggests, but does not confirm, a non-biogenic origin for the ALH84001 carbonates. Copyright (C) 2000 Elsevier Science Ltd.