Ionic liquids as a medium for enantioselective catalysis

被引：98

作者：

Durand, Jerome ^{[1
]}

Teuma, Emmanuelle ^{[1
]}

Gomez, Montserrat ^{[1
]}

机构：

[1] Univ Toulouse 3, CNRS, UMR 5069, Lab Heterochim Fondamentale & Appl, F-31062 Toulouse 9, France

来源：

COMPTES RENDUS CHIMIE | 2007年 / 10卷 / 03期

关键词：

ionic liquids; homogeneous catalysis; enantioselectivity; metal catalysis; biocatalysis; organocatalysis; catalyst recycling;

D O I：

10.1016/j.crci.2006.11.010

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Over the last years, interest involving ionic liquids (ILs) used as reaction medium for homogeneous enantioselective catalysis has exponentially expanded. In many cases, the use of ILs provides several advantages over reactions in organic solvents in terms of activity and enantioselectivity. Even more important, the catalyst immobilization in IL can avoid its leaching and consequently favour its recycling. This review deals with recent advances in the investigation of these new solvents in asymmetric catalysis. We go over enzymes, chiral organocatalysts and metal complexes containing chiral ligands used in enantioselective processes using ionic liquids, with special emphasis on the catalyst reuse and also the separation of organic products.

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页码：152 / 177

页数：26

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