Systematic synthesis of a series of hydroperoxo-, alkylperoxo- and μ-peroxo-palladium complexes supported by the hydrotris(3,5-diisopropylpyrazolyl)borate ligand (TpiPr), TpiPrPd(py)-OOX [X = PdTpiPr(py), H, But], via dehydrative condensation of a hydroxo complex, TpiPrPd(py)-OH

被引：46

作者：

Akita, M ^{[1
]}

Miyaji, T ^{[1
]}

Hikichi, S ^{[1
]}

Moro-oka, Y ^{[1
]}

机构：

[1] Tokyo Inst Technol, Resources Utilizat Res Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 09期

关键词：

D O I：

10.1039/a801111g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of hydroperoxo, tert-butylperoxo and mu-peroxo complexes of palladium, Tp(iPr)Pd(py)(OOX) [X = H, Bu-t, PdTp(iPr)(py); Tp(iPr): hydrotris(3,5-diisopropylpyrazolyl)borate] is prepared by dehydrative condensation of a hydroxo complex, Tp(iPr)Pd(py)(OH), with HOOX.

引用

页码：1005 / 1006

页数：2

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