Synthesis and characterization of allylic dihaloboranes

被引：8

作者：

Le Serre, S ^{[1
]}

Guillemin, JC ^{[1
]}

机构：

[1] Ecole Natl Super Chim Rennes, Lab Synth & Activat Biomol, CNRS, ESA 6052, F-35700 Rennes, France

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 26期

关键词：

D O I：

10.1021/om9706471

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Volatile allylic dihaloboranes have been prepared and characterized by H-1, B-11, C-13, and F-19 NMR spectroscopy and mass spectrometry. The stability (tau(1/2)) of such compounds in dilute CDCl3 solutions depends on the substituents and the halides and ranges from a few minutes (allylic dibromoboranes) to several days (allylic difluoroboranes). Allyldihaloborane etherates were obtained by addition of diethyl ether to the corresponding free allyldihaloborane.

引用

页码：5844 / 5848

页数：5

共 34 条

[1] BOOTH HS, 1939, INORGANIC SYNTHESES, V1, P21
[2] CYCLOPROPYLBORANES AND CARBONIUM ION ANALOGY
COWLEY, AH
FURTSCH, TA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (01) : 39 - &
[3] CHEMICAL AND SPECTROSCOPIC EVIDENCE FOR OCCURRENCE OF PI-CHARACTER IN CARBON-BORON BONDS
COYLE, TD
STONE, FGA
STAFFORD, SL
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1961, (JUL): : 3103 - &
[4] ON THE LEWIS ACID-INDUCED ADDITION OF ALLYLSTANNANES TO ALDEHYDES - A SPECTROSCOPIC INVESTIGATION
DENMARK, SE
WILSON, T
WILLSON, TM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (03) : 984 - 986
[5] Total synthesis of tryprostatin B: Generation of a nucleophilic prenylating species from a prenylstannane
Depew, KM
Danishefsky, SJ
Rosen, N
SeppLorenzino, L
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (49) : 12463 - 12464
[6] PROPERTIES OF TETRAALLYLSILANE TETRAALLYLGERMANE AND TETRAALYLTIN-TIN
FISHWICK, M
WALLBRIDGE, MG
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1970, 25 (01) : 69 - +
[7] POSSIBLE REARRANGEMENT IN REACTION OF BETA-ETHYLENIC BROMIDES WITH MAGNESIUM
GERARD, F
MIGINIAC, P
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1976, 111 (01) : 17 - 30
[8] PRIMARY AND SECONDARY VINYLARSINES - SYNTHESIS, STABILITY, AND CHARACTERIZATION
GUILLEMIN, JC
LASSALLE, L
[J]. ORGANOMETALLICS, 1994, 13 (04) : 1525 - 1527
[9] GERMANE PHOTOCHEMISTRY - PHOTOLYSIS OF GAS-MIXTURES OF PLANETARY INTEREST
GUILLEMIN, JC
LASSALLE, L
JANATI, T
[J]. PLANETARY AND SPACE SCIENCE, 1995, 43 (1-2) : 75 - 81
[10] SYNTHESIS AND CHARACTERIZATION OF ETHYLIDYNEARSINE
GUILLEMIN, JC
LASSALLE, L
DREAN, P
WLODARCZAK, G
DEMAISON, J
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (20) : 8930 - 8936

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