Meisenheimer complexes positively characterized as stable intermediates in the gas phase

被引：66

作者：

Chiavarino, Barbara

Crestoni, Maria Elisa

Fornarini, Simonetta

Lanucara, Francesco

Lemaire, Joel

Maitre, Philippe

机构：

[1] Univ Roma La Sapienza, Dipartimento Studi Chim & Tecnol Sostanze Biol At, I-00185 Rome, Italy

[2] Univ Paris Sud 11, Fac Sci Orsay, Chim Phys Lab, UMR8000, F-91405 Orsay, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 12期

关键词：

anionic sigma complexes; IR spectroscopy; mass spectrometry; photodissociation; structure elucidation;

D O I：

10.1002/anie.200604630

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Graph Presented) Proof positive: Infrared multiphoton dissociation (IRMPD) spectroscopy, with the tunable IR radiation of a free-electron laser source, provides positive identification of alkoxide adducts of 1,3,5-trinitrobenzene as prototypical anionic o complexes in the gas phase (see calculated IR spectrum of 1 under the experimental IRMPD spectrum; N blue, O green, Cgray, H light gray). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：1995 / 1998

页数：4

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