The synthesis of new planar chiral heterobidentate chelate ligands for asymmetric catalysis

被引：19

作者：

Anderson, JC ^{[1
]}

Osborne, J ^{[1
]}

机构：

[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England

来源：

TETRAHEDRON-ASYMMETRY | 2005年 / 16卷 / 05期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1016/j.tetasy.2005.01.026

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of new heterobidentate N,S; N,O and N,P chelate ligands have been synthesised where the sole source of chirality is derived from a planar chiral ferrocene unit and have been shown to give up to 79% ee (R) in the palladium catalysed allylic substitution reaction, suggesting that they may be suitable in other palladium catalysed processes. (C) 2005 Elsevier Ltd. All rights reserved.

引用

页码：931 / 934

页数：4

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