CVD growth and field emission characteristics of nano-structured films composed of vertically standing and mutually intersecting nano-carbon sheets

被引:28
作者
Wang, Jiayu [1 ]
Ito, Toshimichi [1 ]
机构
[1] Osaka Univ, Grad Sch Engn, Dept Elect Engn, Suita, Osaka 5650871, Japan
关键词
nano-structures; plasma CVD; field emission; electrical properties characterization;
D O I
10.1016/j.diamond.2006.11.046
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Nano-structured films composed of rather flat nano-carbon sheets which roughly stood vertically on Si wafers and which intersected each other at large angles were grown by means of a high-power microwave-plasma chemical-vapour-deposition (MWPCVD) method. The structure of the fabricated films was investigated using scanning electron microscopes and Raman spectroscopy. Field emission (FE) currents obtained from these films reached 50 mA/cm(2) at a macroscopic electric field of 3.6 V/mu m. The observed FE characteristics were analyzed using a modified Fowler-Nordheim (F-N) equation where the field enhancement factor and effective emission area were treated as field-dependent parameters. It was found from the analysis that the vertically standing nano-carbon flat sheets had larger field enhancement factors and less FE areas, compared with those obtained for wrinkled namo-carbon sheets previously reported by the authors. It is suggested that the observed variations in the FE current without saturation behavior as a function of the macroscopic electric field can be explained in terms of an effective surface geometry phenomenon of the concerned films. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:589 / 593
页数:5
相关论文
共 21 条
[1]   New mechanism for electron emission from planar cold cathodes: The solid-state field-controlled electron emitter [J].
Binh, VT ;
Adessi, C .
PHYSICAL REVIEW LETTERS, 2000, 85 (04) :864-867
[2]   Field-emission-induced luminescence from carbon nanotubes [J].
Bonard, JM ;
Stockli, T ;
Maier, F ;
de Heer, WA ;
Chatelain, A ;
Salvetat, JP ;
Forro, L .
PHYSICAL REVIEW LETTERS, 1998, 81 (07) :1441-1444
[3]   Field penetration induced charge redistribution effects on the field emission properties of carbon nanotubes - a first-principle study [J].
Chen, CW ;
Lee, MH ;
Clark, SJ .
APPLIED SURFACE SCIENCE, 2004, 228 (1-4) :143-150
[4]  
ITO T, UNPUB
[5]   Diamond/sp2-bonded carbon structures:: quantum well field electron emission? [J].
Karabutov, AV ;
Frolov, VD ;
Konov, VI .
DIAMOND AND RELATED MATERIALS, 2001, 10 (3-7) :840-846
[6]   Effect of surface treatment on the electron field emission property of nano-diamond films [J].
Lee, YC ;
Pradhan, D ;
Lin, SJ ;
Chia, CT ;
Cheng, HF ;
Lin, IN .
DIAMOND AND RELATED MATERIALS, 2005, 14 (11-12) :2055-2058
[7]   Energy band structure effect of individual single-walled carbon nanotubes on field emission characteristics [J].
Liu, XH ;
Zhu, CC ;
Li, YK .
PHYSICA B-CONDENSED MATTER, 2004, 344 (1-4) :243-248
[8]   Low-field electron emission from nano-carbons [J].
Obraztsov, A ;
Zakhidov, AA .
DIAMOND AND RELATED MATERIALS, 2004, 13 (4-8) :1044-1049
[9]   Non-classical electron field emission from carbon materials [J].
Obraztsov, AN ;
Zakhidov, AA ;
Volkov, AP ;
Lyashenko, DA .
DIAMOND AND RELATED MATERIALS, 2003, 12 (3-7) :446-449
[10]  
Prelas MA., 1998, HDB IND DIAMONDS DIA