Palladium pincer-complex catalyzed allylation of tosylimines by potassium trifluoro(allyl)borates

被引：100

作者：

Solin, N ^{[1
]}

Wallner, OA ^{[1
]}

Szabó, KJ ^{[1
]}

机构：

[1] Univ Stockholm, Arrhenius Lab, Dept Organ Chem, SE-10691 Stockholm, Sweden

来源：

ORGANIC LETTERS | 2005年 / 7卷 / 04期

关键词：

D O I：

10.1021/ol0475010

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Palladium pincer complex 1 catalyzes the reaction of trifluoro(allyl)borate 2 with a wide range of tosylimines (3) under mild and neutral reaction conditions. This catalytic transformation affords homoallylic annines (4) in good to excellent yield. Mechanistic studies suggest that a transmetalation reaction between complex 1 and the borate salt 2 provides an eta(1)-allyipalladium complex, which subsequently reacts with the imine substrate.

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页码：689 / 691

页数：3

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