The titanocene complex of bis(trimethylsilyl)acetylene: Synthesis, structure, and chemistry

被引：210

作者：

Rosenthal, U ^{[1
]}

Burlakov, VV ^{[1
]}

Arndt, P ^{[1
]}

Baumann, W ^{[1
]}

Spannenberg, A ^{[1
]}

机构：

[1] Univ Rostock, Leibniz Inst Organ Katalyse, D-18055 Rostock, Germany

来源：

ORGANOMETALLICS | 2003年 / 22卷 / 05期

关键词：

D O I：

10.1021/om0208570

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis, structure and chemistry of titanocene Complex of bis(trimethylsilyl)acetylene were discussed. It was found that during high-vacuum sublimation the complex slowly decomposed and did not provided good crystals. The advantages of titanocene complex along with other complexes over other widely used titanocene-generating systems were also presented.

引用

页码：884 / 900

页数：17

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