Scattering functions of polymeric core-shell structures and excluded volume chains

被引:99
作者
Forster, S [1 ]
Burger, C [1 ]
机构
[1] Max Planck Inst Colloids & Interfaces, D-14513 Teltow, Germany
关键词
D O I
10.1021/ma970761v
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
General expressions for the scattering functions of polydisperse particles with an arbitrary number of concentric shells of lamellar, cylindrical, or spherical symmetry are derived. For shells consisting of dense polymer layers or brushes with algebraic density profiles, phi(r) similar to r(alpha), it is possible to obtain closed analytical expressions by taking advantage of the mathematical properties of hypergeometric functions. The same formalism can be employed to derive a closed expression for the form factor of polydisperse excluded volume chains assuming a des Cloizeaux-type segment distribution function.
引用
收藏
页码:879 / 891
页数:13
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