Cuvette-Based Electrogenerated Chemiluminescence Detection System for the Assessment of Polymerizable Ruthenium Luminophores

被引：9

作者：

Danis, Andrew S. ^{[1
]}

Odette, William L. ^{[1
]}

Perry, Samuel C. ^{[1
]}

Canesi, Sylvain ^{[2
]}

Sleiman, Hanadi F. ^{[1
]}

Mauzeroll, Janine ^{[1
]}

机构：

[1] McGill Univ, Dept Chem, 801 Sherbrooke St West, Montreal, PQ H3A 0B8, Canada

[2] Univ Quebec, Dept Chim, CP 8888,Succ Ctr Ville, Montreal, PQ H3C 3P8, Canada

来源：

CHEMELECTROCHEM | 2017年 / 4卷 / 07期

基金：

加拿大自然科学与工程研究理事会;

关键词：

cuvette; electrogenerated chemiluminescence; tripropylamine; tris(2,2 '-bipyridine)ruthenium(II); ring-opening metathesis polymerization; ELECTROCHEMILUMINESCENCE; OXIDATION; EMISSION;

D O I：

10.1002/celc.201600879

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Herein, we validate a novel cuvette-based approach to measure electrogenerated chemiluminescence (ECL) by employing the hyphenation of a commercial spectrometer and a potentiostat. The new experimental design provides simultaneous acquisition of electrochemical and ECL data, allowing complementary analysis by both techniques. Preliminary analysis of an organometallic ECL standard, tris(2,2'-bipyridine) ruthenium(II) (Ru(bpy)(3) (2+)), and tripropylamine (TPA), showed excellent reproducibility both in terms of the electrochemistry and the ECL signal. Equally as important, the acquired electrochemistry and ECL from the Ru(bpy)(3)(2+)/TPA system served as a baseline for evaluating the ECL response of polymerizable ruthenium luminophores.

引用

页码：1736 / 1743

页数：8

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