Deoxygenation of sulfoxides and selenoxides with nickel boride

被引：57

作者：

Khurana, JM ^{[1
]}

Ray, A ^{[1
]}

Singh, S ^{[1
]}

机构：

[1] Univ Delhi, Dept Chem, Delhi 110007, India

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 22期

关键词：

D O I：

10.1016/S0040-4039(98)00623-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The deoxygenations of a variety of acyclic sulfoxides and selenoxides have been reported with nickel boride in THF at 0-5 degrees C in nearly quantitative yields. The deoxygenations are proposed to proceed by an oxidative-addition and reductive-elimination mechanism. (C) 1998 Elsevier Science Ltd. All rights reserved.

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页码：3829 / 3832

页数：4

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