Synthetic applications .1. of the tandem [2,3]-Wittig-anionic oxy-cope rearrangement: Stereoselective disubstituted tetrahydropyran synthesis by electrophile initiated cyclisation

被引：16

作者：

Greeves, N

Lee, WM

机构：

[1] Robert Robinson Laboratories, Department of Chemistry, University of Liverpool, Liverpool L69 7ZD, Crown St.

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 36期

关键词：

D O I：

10.1016/S0040-4039(97)01474-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reduction of the delta,epsilon-unsaturated aldehydes produced by tandem [2,3]-Wittig-anionic oxy-Cope rearrangement followed by stereoselective electrophilic cyclisation and reductive removal of the electrophile leads to single diastereoisomers of tetrahydropyrans. (C) 1997 Elsevier Science Ltd.

引用

页码：6449 / 6452

页数：4

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