Dehydrogenative coupling of hydrostannanes catalyzed by transition-metal complexes

被引：70

作者：

Braunstein, P ^{[1
]}

Morise, X ^{[1
]}

机构：

[1] Univ Strasbourg 1, UMR 7513 CNRS, Chim Coordinat Lab, Inst Le Bel, F-67070 Strasbourg, France

来源：

CHEMICAL REVIEWS | 2000年 / 100卷 / 10期

关键词：

D O I：

10.1021/cr000444d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The transition-metal-catalyzed dehydrogenative coupling of hydrostannanes were studied as valuable catalysts for synthesis of high molecular weight polystannanes. Catalytic dehydrogenative coupling took place in various steps where the alkosilyl or siloxysilyl ligands helped in the process. A very high activation energy was observed.

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页码：3541 / 3552

页数：12

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