Linear 1,4-coupled oligoanilines of defined length:: preparation and spectroscopic properties

被引：56

作者：

Rózalska, I ^{[1
]}

Kulyk, P ^{[1
]}

Kulszewicz-Bajer, I ^{[1
]}

机构：

[1] Warsaw Univ Technol, Fac Chem, PL-00664 Warsaw, Poland

来源：

NEW JOURNAL OF CHEMISTRY | 2004年 / 28卷 / 10期

关键词：

D O I：

10.1039/b404828h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A facile synthetic method involving SNAr coupling of 4-fluoronitrobenzene to arylamines, followed by reduction of the nitro groups, has been developed. The method allows the preparation of symmetric (NH2/NH2 end-capped) and asymmetric (Ph/NH2 end-capped) oligoanilines of even or odd chain lengths. The preparation of the NH2/NH2 end-capped trimer to octamer and Ph/NH2 end-capped trimer to pentamer is described. The effect of the chain length on the spectroscopic properties of the oxidized oligomers has been investigated by UV-Vis-NIR spectroscopy.

引用

页码：1235 / 1243

页数：9

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