Synthesis of fluorinated block copolymers and their application as novel polymerisation surfactants in supercritical carbon dioxide

被引：42

作者：

Yong, TM

Hems, WP

vanNunen, JLM

Holmes, AB

Steinke, JHG

Taylor, PL

Segal, JA

Griffin, DA

机构：

[1] UNIV CAMBRIDGE,DEPT CHEM,CAMBRIDGE CB2 1EW,ENGLAND

[2] UNIV CAMBRIDGE,DEPT CHEM,MELVILLE LAB POLYMER SYNTH,CAMBRIDGE CB2 3RA,ENGLAND

[3] ICI PAINTS,DECORAT RES,SLOUGH SL2 5DS,BERKS,ENGLAND

[4] ICI ACRYL,MIDDLESBROUGH TS90 8JE,CLEVELAND,ENGLAND

[5] ZENECA AGROCHEM,JEALOTTS HILL RES STN,BRACKNELL RG12 6EY,BERKS,ENGLAND

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 18期

关键词：

D O I：

10.1039/a705399a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Screened anionic copolymerisation of methyl methacrylate with the perfluoroalkyl methacrylates 2 affords well-defined AB block copolymers 4-6, which serve as effective surfactants in the dispersion polymerisation of methyl methacrylate in supercritical carbon dioxide.

引用

页码：1811 / 1812

页数：2

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