Enthalpy driven nitrate complexation by guanidinium-based macrocycles

被引：35

作者：

Blondeau, Pascal ^{[1
]}

Benet-Buchholz, Jordi ^{[1
]}

de Mendoza, Javier ^{[1
]}

机构：

[1] Inst Chem Res Catalonia ICIQ, Tarragona 43007, Spain

来源：

NEW JOURNAL OF CHEMISTRY | 2007年 / 31卷 / 05期

关键词：

D O I：

10.1039/b616409a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

NMR and isothermal calorimetric titrations, as well as X-ray structures, show the binding of a nitrate anion inside guanidinium-based macrocycles. All six lone pairs of nitrate are complemented by oriented hydrogen bond donors from a guanidinium and two urea subunits.

引用

页码：736 / 740

页数：5

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