Pt- and Au-catalyzed oxidative cyclization of 2-ethenyl-1-(prop-2′-yn-1-′-ol) benzenes to naphthyl aldehydes and ketones:: catalytic oxidation of metal-alkylidene intermediates using H2O and H2O2

被引：50

作者：

Taduri, Bhanu Pratap ^{[1
]}

Abu Sohel, Shariar Md. ^{[1
]}

Cheng, Hsin-Mei ^{[1
]}

Lin, Guan-You ^{[1
]}

Liu, Rai-Shung ^{[1
]}

机构：

[1] Natl Tsing Hua Univ, Dept Chem, Hsinchu, Taiwan

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 24期

关键词：

D O I：

10.1039/b700659d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

2-Ethenyl-1-(prop-2'-yn-1'-ol) benzenes was cyclized through catalytic oxidation with PtCl2/CO/H2O and PEt3AuCl/H2O2; the metal-naphthylidene intermediates were identified and oxygenated with water and H2O2, respectively; for the efficiency of cyclization, the Au catalytic system is superior to that of the PtCl2-catalysis because of its compatibility toward diverse alcohol substrates including both internal alkynes and terminal alkynes.

引用

收藏

页码：2530 / 2532

页数：3

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