A-D-A-type S, N-Heteropentacenes: Next-Generation Molecular Donor Materials for Efficient Vacuum-Processed Organic Solar Cells

被引:84
作者
Mishra, Amaresh [1 ]
Popovic, Dusko [1 ]
Vogt, Astrid [1 ]
Kast, Hannelore [1 ]
Leitner, Tanja [1 ]
Walzer, Karsten [2 ]
Pfeiffer, Martin [2 ]
Mena-Osteritz, Elena [1 ]
Baeuerle, Peter [1 ]
机构
[1] Univ Ulm, Inst Organ Chem & Adv Mat 2, D-89081 Ulm, Germany
[2] Heliatek GmbH, D-01139 Dresden, Germany
关键词
heteroacenes; molecular donors; photovoltaic devices; semiconductors; OLIGOTHIOPHENES;
D O I
10.1002/adma.201402448
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new class of acceptor-substituted S,N-heteropentacenes is developed for vacuum-processed organic solar cells, providing encouraging power conversion efficiencies of up to 6.5%. Atomic force microscopy (AFM) investigations give a direct correlation between the blend film morphology and the photovoltaic parameters, such as short-circuit current density (JSC) and fill factor (FF). © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:7217 / 7223
页数:7
相关论文
共 24 条
[1]   Electrochemical Considerations for Determining Absolute Frontier Orbital Energy Levels of Conjugated Polymers for Solar Cell Applications [J].
Cardona, Claudia M. ;
Li, Wei ;
Kaifer, Angel E. ;
Stockdale, David ;
Bazan, Guillermo C. .
ADVANCED MATERIALS, 2011, 23 (20) :2367-2371
[2]   High Performance Photovoltaic Applications Using Solution-Processed Small Molecules [J].
Chen, Yongsheng ;
Wan, Xiangjian ;
Long, Guankui .
ACCOUNTS OF CHEMICAL RESEARCH, 2013, 46 (11) :2645-2655
[3]   Design and Synthesis of Molecular Donors for Solution-Processed High-Efficiency Organic Solar Cells [J].
Coughlin, Jessica E. ;
Henson, Zachary B. ;
Welch, Gregory C. ;
Bazan, Guillermo C. .
ACCOUNTS OF CHEMICAL RESEARCH, 2014, 47 (01) :257-270
[4]  
Ding L., 2013, ENERG ENVIRON SCI, V6, P3224
[5]   Efficient organic solar cells based on a double p-i-n architecture using doped wide-gap transport layers -: art. no. 244102 [J].
Drechsel, J ;
Männig, B ;
Kozlowski, F ;
Pfeiffer, M ;
Leo, K ;
Hoppe, H .
APPLIED PHYSICS LETTERS, 2005, 86 (24) :1-3
[6]   Correlation of π-Conjugated Oligomer Structure with Film Morphology and Organic Solar Cell Performance [J].
Fitzner, Roland ;
Mena-Osteritz, Elena ;
Mishra, Amaresh ;
Schulz, Gisela ;
Reinold, Egon ;
Weil, Matthias ;
Koerner, Christian ;
Ziehlke, Hannah ;
Elschner, Chris ;
Leo, Karl ;
Riede, Moritz ;
Pfeiffer, Martin ;
Uhrich, Christian ;
Baeuerle, Peter .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (27) :11064-11067
[7]   Dicyanovinyl-Substituted Oligothiophenes: Structure-Property Relationships and Application in Vacuum-Processed Small-Molecule Organic Solar Cells [J].
Fitzner, Roland ;
Reinold, Egon ;
Mishra, Amaresh ;
Mena-Osteritz, Elena ;
Ziehlke, Hannah ;
Koerner, Christian ;
Leo, Karl ;
Riede, Moritz ;
Weil, Matthias ;
Tsaryova, Olga ;
Weiss, Andre ;
Uhrich, Christian ;
Pfeiffer, Martin ;
Baeuerle, Peter .
ADVANCED FUNCTIONAL MATERIALS, 2011, 21 (05) :897-910
[8]   Barium: An Efficient Cathode Layer for Bulk-heterojunction Solar Cells [J].
Gupta, Vinay ;
Kyaw, Aung Ko Ko ;
Wang, Dong Hwan ;
Chand, Suresh ;
Bazan, Guillermo C. ;
Heeger, Alan J. .
SCIENTIFIC REPORTS, 2013, 3
[9]   Organic p-i-n solar cells [J].
Maennig, B ;
Drechsel, J ;
Gebeyehu, D ;
Simon, P ;
Kozlowski, F ;
Werner, A ;
Li, F ;
Grundmann, S ;
Sonntag, S ;
Koch, M ;
Leo, K ;
Pfeiffer, M ;
Hoppe, H ;
Meissner, D ;
Sariciftci, NS ;
Riedel, I ;
Dyakonov, V ;
Parisi, J .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2004, 79 (01) :1-14
[10]   Small Molecule Organic Semiconductors on the Move: Promises for Future Solar Energy Technology [J].
Mishra, Amaresh ;
Baeuerle, Peter .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (09) :2020-2067