Wetting 101°

被引:297
作者
Gao, Lichao [1 ]
McCarthy, Thomas J. [1 ]
机构
[1] Univ Massachusetts, Dept Polymer Sci & Engn, Amherst, MA 01003 USA
基金
美国国家科学基金会;
关键词
CONTACT-ANGLE HYSTERESIS; SUPPORTED TRIS(TRIMETHYLSILOXY)SILYL MONOLAYERS; POLYMER SURFACE MODIFICATION; BY-LAYER DEPOSITION; LIQUID-DROPS; SUPERHYDROPHOBIC SURFACES; LENGTH SCALES; WENZEL; CASSIE; SILICON;
D O I
10.1021/la902206c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We review our 2006-2009 publications oil wetting and superhydrophobicity in a manner designed to serve its a useful primer for those who would like to use the concepts of this Field. We demonstrate that the 1D (three-phase, solid/liquid/vapor) contact line perspective is simpler, more intuitive, more useful, and more consistent with facts than the disproved but widely lield-to-be-correct 2D view. We give an explanation of what we believe to be the reason that the existing theoretical understanding is wrong and argue that the teaching of surface science over the last century has led generations of students and scientists to a misunderstanding of the wetting of solids by liquids. We review our analyses of the phenomena of contact angle hysteresis, the lotus effect, and perfect hydrophobicity and suggest that needlessly complex theoretical understandings, incorrect models, and ill-defined terminology are not useful and can be destructive.
引用
收藏
页码:14105 / 14115
页数:11
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