Free radical polymerization within mesoporous zeolite channels

被引：81

作者：

Ng, SM ^{[1
]}

Ogino, S

Aida, T

Koyano, KA

Tatsumi, T

机构：

[1] Univ Tokyo, Grad Sch Engn, Dept Chem & Biotechnol, Bunkyo Ku, Tokyo 113, Japan

[2] Univ Tokyo, Fac Engn, Engn Res Inst, Bunkyo Ku, Tokyo 113, Japan

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 1997年 / 18卷 / 12期

关键词：

D O I：

10.1002/marc.1997.030181201

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Free radical polymerization of methyl methacrylate (MMA) within the uniform channels of the mesoporous zeolite MCM-41 proceeds at 100 degrees C to give a high molecular weight polymer (PMMA). The formation of long living propagating polymer-radicals is observed by electron paramagnetic resonance (EPR). The molecular weight of PMMA within the mesopores can be controlled over a wide range by changing the monomer-to-initiator mole ratio.

引用

页码：991 / 996

页数：6

共 15 条

[1] A NEW FAMILY OF MESOPOROUS MOLECULAR-SIEVES PREPARED WITH LIQUID-CRYSTAL TEMPLATES [J].

BECK, JS ;

VARTULI, JC ;

ROTH, WJ ;

LEONOWICZ, ME ;

KRESGE, CT ;

SCHMITT, KD ;

CHU, CTW ;

OLSON, DH ;

SHEPPARD, EW ;

MCCULLEN, SB ;

HIGGINS, JB ;

SCHLENKER, JL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) :10834-10843

[2]

DAVIS ME, 1995, ZEOLITE, V12, P33

[3]

HORIE K, 1974, MAKROMOL CHEM, V175, P2091

[4] ESR STUDY OF PROPAGATING RADICAL IN POLYMERIZATION OF MMA IN FROZEN STATE [J].

KAMACHI, M ;

KOHNO, M ;

LIAW, DJ ;

KATSUKI, S .

POLYMER JOURNAL, 1978, 10 (01) :69-75

[5] POLYMERIZATION OF METHYL-METHACRYLATE WITH THE CARBON-TETRACHLORIDE DICHLOROTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) METHYLALUMINUM BIS(2,6-DI-TERT-BUTYLPHENOXIDE) INITIATING SYSTEM - POSSIBILITY OF LIVING RADICAL POLYMERIZATION [J].

KATO, M ;

KAMIGAITO, M ;

SAWAMOTO, M ;

HIGASHIMURA, T .

MACROMOLECULES, 1995, 28 (05) :1721-1723

[6] LIVING RADICAL POLYMERIZATIONS OF VINYL MONOMERS INITIATED BY AGED CR2++BPO IN HOMOGENEOUS SOLUTION [J].

LEE, M ;

MORIGAMI, T ;

MINOURA, Y .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1978, 74 :1738-1749

[7] FUNCTIONAL MONOMERS AND POLYMERS .142. INCLUSION POLYMERIZATION OF DIENE MONOMERS IN DEOXYCHOLIC-ACID AND APOCHOLIC ACID CANALS BY FREE-RADICAL INITIATORS [J].

MIYATA, M ;

NOMA, F ;

OSAKI, Y ;

TAKEMOTO, K ;

KAMACHI, M .

JOURNAL OF POLYMER SCIENCE PART C-POLYMER LETTERS, 1986, 24 (09) :457-461

[8] Polymers with very low polydispersities from atom transfer radical polymerization [J].

Patten, TE ;

Xia, JH ;

Abernathy, T ;

Matyjaszewski, K .

SCIENCE, 1996, 272 (5263) :866-868

[9]

QUAEGEBEUR JP, 1976, J POLYM SCI POL CHEM, V14, P2703, DOI 10.1002/pol.1976.170141112

[10]

RYCHLY J, 1972, EUR POLYM J, P711

← 1 2 →