First end-to-end thiocyanato chain containing 5-coordinate copper(II) ions

被引：23

作者：

Gómez-Saiz, P

García-Tojal, J

Arnáiz, FJ

Maestro, MA

Lezama, L

Rojo, T

机构：

[1] Univ Burgos, Dpto Quim, Burgos 09001, Spain

[2] Univ A Coruna, Serv Gen Apoyo Invest, Edificio Anexo Fac Ciencias, La Coruna 15071, Spain

[3] Univ Basque Country, Dpto Quim Inorgan, Bilbao 48080, Spain

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2003年 / 6卷 / 05期

关键词：

copper(II) complexes; oxadiazole complexes; thiocyanato complexes;

D O I：

10.1016/S1387-7003(03)00038-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and crystal structure of a new [{Cu(L)(NCS)(2)}(n)] complex where L = (C8H8N4O) = 2-methylamino-5-pyridin-2-yl-1,3,4-oxadiazole are reported. The structure is made up of ID-chains containing monomeric copper(II) units linked by thiocyanato groups which act as end-to-end bridges. The metal ions show a 5-coordinate environment with a stereochemistry close to SP where the basal plane positions are occupied by the N-donor atoms of the bidentate L ligand, a bridging and a terminal thiocyanato group. The apical site is occupied by an S-donor atom from the neighbor molecule. The shortest copper...copper distances are 5.599(6) Angstrom. A paramagnetic behavior is observed in this compound. (C) 2003 Elsevier Science B.V. All rights reserved.

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页码：558 / 560

页数：3

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