Photochemical production of nitric oxide via two-photon excitation with NIR light

被引：78

作者：

Wecksler, S ^{[1
]}

Mikhailovsky, A ^{[1
]}

Ford, PC ^{[1
]}

机构：

[1] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 42期

关键词：

D O I：

10.1021/ja045710+

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Herein we demonstrate the successful photochemical generation of nitric oxide via two-photon excitation (TPE) from the supramolecular complex PPIX-RSE ({μ-S,μ-S-protoporphyrin-IX-bis(2-thioethyl)diester]tetranitrosyl-diiron). The TPE fluorescence spectra indicate efficient energy transfer from the PPIX antennae to the iron sulfur nitrosyl cluster. Further evidence of NO release is demonstrated using a nitric oxide specific electrode and ESI+ MS. Copyright © 2004 American Chemical Society.

引用

页码：13566 / 13567

页数：2

共 27 条

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