Fluid-liquid and fluid-solid transitions of poly(ethylene-co-octene-1) in sub- and supercritical propane solutions

被引：25

作者：

Chan, KC

Adidharma, H

Radosz, M

机构：

[1] Louisiana State Univ, Dept Chem Engn, Baton Rouge, LA 70803 USA

[2] Louisiana State Univ, Macromol Studies Grp, Baton Rouge, LA 70803 USA

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2000年 / 39卷 / 08期

关键词：

D O I：

10.1021/ie990761e

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Fluid-liquid (FL) and fluid-solid (FS) phase transitions are measured and correlated with two SAFT equations of state for poly(ethylene-co-octene-1) solutions in sub- and supercritical propane. The polymer concentration is found to have a weak effect on both FL and FS transitions in the range of this study (0.01-0.1 polymer weight fraction). Increasing molecular weight is found to increase the FL pressure and FS temperature, whereas increasing branch density is found to decrease the FL pressure and FS temperature.

引用

页码：3069 / 3075

页数：7

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