Tetrakis(acetonitrile-N)copper(I) tetrafluoroborate

被引：32

作者：

Jones, PG ^{[1
]}

Crespo, O ^{[1
]}

机构：

[1] Tech Univ Braunschweig, Inst Anorgan & Analyt Chem, D-38023 Braunschweig, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1998年 / 54卷

关键词：

D O I：

10.1107/S0108270197013322

中图分类号：

O6 [化学];

学科分类号：

0703 [化学];

摘要：

The title compound, [Cu(H3CCN)(4)]BF4, is isomorphous with the analogous compounds [M(H3CCN)(4)]ClO4 (M = Cu, Ag). It contains three independent formula units. A large spread of values of chemically equivalent dimensions is observed, notably in the cations, which display tetrahedral coordination at copper, with Cu-N 1.964 (6)-2.028 (6) Angstrom (average 1.993 Angstrom) and N-Cu-N 105.4 (2)-113.4 (2)degrees (average 109.4 degrees).

引用

页码：18 / 20

页数：3

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