Synthesis and characterization of new acrylate and methacrylate monomers with pendant pyridine groups

被引：21

作者：

Cui, L ^{[1
]}

Lattermann, G ^{[1
]}

机构：

[1] Univ Bayreuth, D-95440 Bayreuth, Germany

来源：

MACROMOLECULAR CHEMISTRY AND PHYSICS | 2002年 / 203卷 / 17期

关键词：

atom transfer radical polymerization (ATRP); monomers; polyacrylates; polycations; polymethacrylates; synthesis;

D O I：

10.1002/macp.200290020

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

To overcome some drawbacks of polyvinylpyridines, new monomers of acrylate and methacrylate type with pendant pyridine groups i.e., 4-(3-methacrylolpropyl)pyridine 1a and 4-(3-acryloylpropyl)pryridine 1b were successfully prepared, although it turned out to be challenging work to synthesize the acrylate monomer 1b. First polymerized easily by atom transfer radicaal polymerization (ATRP). The new polymers show excellent characteristics, such as very good solubility, low glass-transition temperature, and easy quaternization.

引用

页码：2432 / 2437

页数：6

共 13 条

[1] ANNELATION OF PYRIDINIUM RINGS ONTO NITROGEN-HETEROCYCLES [J].