Preparation of polyaniline coated poly(methyl methacrylate) microsphere by graft polymerization and its electrorheology

被引：83

作者：

Lee, IS ^{[1
]}

Cho, MS ^{[1
]}

Choi, HJ ^{[1
]}

机构：

[1] Inha Univ, Dept Polymer Sci & Engn, Inchon 402751, South Korea

来源：

POLYMER | 2005年 / 46卷 / 04期

关键词：

polyaniline; microsphere; electrorheology;

D O I：

10.1016/j.polymer.2004.11.068

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Monodisperse acrylic microspheres (diameter 9.2 mum) (An-PGMA) with aniline moieties on the surface were initially prepared by a seeded emulsion method, and then composite particles (PA-PGMA) possessing polyaniline (PANI) shell were prepared via an in situ polymerization of aniline using An-PGMA particles as a core material inducing grafting polymerization of aniline. The PANI layer was found to be formed on the An-PGMA surface from the microscopic image, C-13 FT-NMR and TGA of the PA-PGMA particles. Suspension of the PA-PGMA particle dispersed in silicone oil showed typical electrorheological (ER) characteristics under external electric fields. (C) 2005 Elsevier Ltd. All rights reserved.

引用

页码：1317 / 1321

页数：5

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