Molecular imprinting of azobenzene carboxylic acid on a TiO2 ultrathin film by the surface sol-gel process

被引:140
作者
Lee, SW [1 ]
Ichinose, I [1 ]
Kunitake, T [1 ]
机构
[1] Kyushu Univ, Fac Engn, Dept Chem Sci & Technol, Fukuoka 812, Japan
关键词
D O I
10.1021/la9801763
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Ultrathin films of titanium oxide gel imprinted with 4-(4-propyloxyphenylazo)benzoic acid (C(3)AzoCO(2)H) were prepared by repeated immersion of a gold-coated quartz crystal microbalance (QCM) electrode or a quartz plate in solutions of C(3)AzoCO(2)H and titanium butoxide (Ti(O-nBu)(4)) in toluene/ethanol. Regular film growth was confirmed by frequency decrement in QCM measurements and by the appearance of the azobenzene absorption in UV-vis spectroscopy. The template molecule could be completely removed upon treatment with 1% aqueous ammonia, The resulting films showed saturation binding of the template molecule in acetonitrile in less than 1 min. Binding of the template molecule was greatest among aromatic carboxylic acids that are structurally related to the template. A related ester showed a significant reduction in the binding efficiency. The surface sol-gel process provides a powerful tool for molecular imprinting in ultrathin metal oxide films.
引用
收藏
页码:2857 / 2863
页数:7
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