Solvent free base catalysis and transesterifiation over basic functionalised Metal-Organic Frameworks

被引:123
作者
Savonnet, Marie [1 ,2 ]
Aguado, Sonia [1 ]
Ravon, Ugo [1 ]
Bazer-Bachi, Delphine [2 ]
Lecocq, Vincent [2 ]
Bats, Nicolas [2 ]
Pinel, Catherine [1 ]
Farrusseng, David [1 ]
机构
[1] Univ Lyon 1, CNRS, IRCELYON, UMR 5256, 2 Ave Albert Einstein, F-69626 Villeurbanne, France
[2] IFP Lyon, F-69360 Solaize, France
关键词
SUPPORTS; SILICAS;
D O I
10.1039/b915291c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Metal-Organic Frameworks (post-)functionalised with nitrogen containing moieties undergo solvent free aza-Michael condensation and transesterification, surpassing molecular and functionalised MCM-type analogues.
引用
收藏
页码:1729 / 1732
页数:4
相关论文
共 19 条
[1]   New trends in the design of supported catalysts on mesoporous silicas and their applications in fine chemicals [J].
Brunel, D ;
Blanc, AC ;
Galarneau, A ;
Fajula, F .
CATALYSIS TODAY, 2002, 73 (1-2) :139-152
[2]  
Brunel D, 1995, STUD SURF SCI CATAL, V97, P173
[3]   Chemical modification of a bridging ligand inside a metal-organic framework while maintaining the 3D structure [J].
Costa, Jose Sanchez ;
Gamez, Patrick ;
Black, Cory A. ;
Roubeau, Olivier ;
Teat, Simon J. ;
Reedijk, Jan .
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2008, (10) :1551-1554
[4]   Covalent modification of a metal-organic framework with isocyanates: probing substrate scope and reactivity [J].
Dugan, Emily ;
Wang, Zhenqiang ;
Okamura, Marilyn ;
Medina, Annette ;
Cohen, Seth M. .
CHEMICAL COMMUNICATIONS, 2008, (29) :3366-3368
[5]  
FARRUSSENG D, 2009, DESIGN HETEROGENEOUS
[6]   Hybrid porous solids:: past, present, future [J].
Ferey, Gerard .
CHEMICAL SOCIETY REVIEWS, 2008, 37 (01) :191-214
[7]   Thermal and mechanical stability of micelle-templated silica supports for catalysis [J].
Galarneau, A ;
Desplantier-Giscard, D ;
Di Renzo, F ;
Fajula, F .
CATALYSIS TODAY, 2001, 68 (1-3) :191-200
[8]   Connecting small ligands to generate large tubular metal-organic architectures [J].
Goforth, AM ;
Su, CY ;
Hipp, R ;
Macquart, RB ;
Smith, MD ;
zur Loye, HC .
JOURNAL OF SOLID STATE CHEMISTRY, 2005, 178 (08) :2511-2518
[9]   Proton and water activity-controlled structure formation in zinc carboxylate-based metal organic frameworks [J].
Hausdorf, Steffen ;
Wagler, Joerg ;
Mossig, Regina ;
Mertens, Florian O. R. L. .
JOURNAL OF PHYSICAL CHEMISTRY A, 2008, 112 (33) :7567-7576
[10]   Gaseous species as reaction tracers in the solvothermal synthesis of the zinc oxide terephthalate MOF-5 [J].
Hausdorf, Steffen ;
Baitalow, Felix ;
Seidel, Juergen ;
Mertens, Florian O. R. L. .
JOURNAL OF PHYSICAL CHEMISTRY A, 2007, 111 (20) :4259-4266