Carbon nanotube-reinforced epoxy-compo sites:: enhanced stiffness and fracture toughness at low nanotube content

被引:1213
作者
Gojny, FH
Wichmann, MHG
Köpke, U
Fiedler, B
Schulte, K
机构
[1] Tech Univ Hamburg, Polymer Composites Sect, D-21073 Hamburg, Germany
[2] Exakt GmbH & Co KG, D-22851 Norderstedt, Germany
关键词
carbon nanotubes;
D O I
10.1016/j.compscitech.2004.04.002
中图分类号
TB33 [复合材料];
学科分类号
摘要
Nanocomposites consisting of double-wall carbon nanotubes (DWCNTs) and an epoxy matrix were produced by a standard calandering technique. A very good dispersion of both DWCNTs and carbon black (CB) in an epoxy resin could be observed. The investigation of the (fracture-) mechanical properties resulted in an increase of strength, Young's modulus and strain to failure at a nanotube content of only 0.1 wt%. The correlation of the experimentally obtained Young's moduli showed a good agreement with a modified Halpin-Tsai theory. In addition a significantly improved fracture toughness could be observed for the nanocomposites. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2363 / 2371
页数:9
相关论文
共 25 条
[1]   ALIGNED CARBON NANOTUBE ARRAYS FORMED BY CUTTING A POLYMER RESIN-NANOTUBE COMPOSITE [J].
AJAYAN, PM ;
STEPHAN, O ;
COLLIEX, C ;
TRAUTH, D .
SCIENCE, 1994, 265 (5176) :1212-1214
[2]   Mechanical and electrical properties of a MWNT/epoxy composite [J].
Allaoui, A ;
Bai, S ;
Cheng, HM ;
Bai, JB .
COMPOSITES SCIENCE AND TECHNOLOGY, 2002, 62 (15) :1993-1998
[3]   Measurement of carbon nanotube-polymer interfacial strength [J].
Barber, AH ;
Cohen, SR ;
Wagner, HD .
APPLIED PHYSICS LETTERS, 2003, 82 (23) :4140-4142
[4]   Detachment of nanotubes from a polymer matrix [J].
Cooper, CA ;
Cohen, SR ;
Barber, AH ;
Wagner, HD .
APPLIED PHYSICS LETTERS, 2002, 81 (20) :3873-3875
[5]   Molecular simulation of the influence of chemical cross-links on the shear strength of carbon nanotube-polymer interfaces [J].
Frankland, SJV ;
Caglar, A ;
Brenner, DW ;
Griebel, M .
JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (12) :3046-3048
[6]   Surface modified multi-walled carbon nanotubes in CNT/epoxy-composites [J].
Gojny, FH ;
Nastalczyk, J ;
Roslaniec, Z ;
Schulte, K .
CHEMICAL PHYSICS LETTERS, 2003, 370 (5-6) :820-824
[7]  
GOJNY FH, 2004, COMPOS SCI TECHNOL
[8]  
HALPIN JC, 1969, 67423 AFMLTR
[9]   HELICAL MICROTUBULES OF GRAPHITIC CARBON [J].
IIJIMA, S .
NATURE, 1991, 354 (6348) :56-58
[10]   Electrically conductive glass fibre reinforced epoxy resin [J].
Kupke, M ;
Wentzel, HP ;
Schulte, K .
MATERIALS RESEARCH INNOVATIONS, 1998, 2 (03) :164-169