Xeniaoxolane:: A new xenicane-type diterpenoid from the Okinawan soft coral, Xenia sp.;: Absolute configurations of xeniaoxolane, xeniolide-A and xenialactol

被引:24
作者
Miyaoka, H [1 ]
Mitome, H [1 ]
Nakano, M [1 ]
Yamada, Y [1 ]
机构
[1] Tokyo Univ Pharm & Life Sci, Sch Pharm, Hachioji, Tokyo 1920392, Japan
关键词
marine metabolites; natural products; terpenes and terpenoids;
D O I
10.1016/S0040-4020(00)00689-X
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A new xenicane-type diterpenoid, xeniaoxolane, containing tetrahydrofuran, was isolated from the Okinawan soft coral of the genus, Xenia along with xeniolide-A and xenialactol. The relative configuration of xeniaoxolane was determined based on spectroscopic analysis. The absolute configuration of xeniolide-A was determined using the modified Mosher's method and those of xeniaoxolane and xenialactol, by chemical conversions. (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:7737 / 7740
页数:4
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