Comparative investigation of the Group 6 (Cr, Mo or W) metal carbonyl complexes of 1,3,5-triazacyclohexanes

被引：35

作者：

Armanasco, NL ^{[1
]}

Baker, MV ^{[1
]}

North, MR ^{[1
]}

Skelton, BW ^{[1
]}

White, AH ^{[1
]}

机构：

[1] Univ Western Australia, Dept Chem, Nedlands, WA 6907, Australia

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1998年 / 07期

关键词：

D O I：

10.1039/a708888d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation and characterisation of 1,3,5-trialkyl-1,3,5-triazacyclohexane complexes of Group 6 metal carbonyls [M(CO)(3)(C3H6N3R3)] (R = Me or Bu-t, M = Mo or W; R = CH2Ph, M = Mo) are reported. The complexes have been characterised by NMR, IR spectroscopy and mass spectrometry. Their spectroscopic properties and reactivity are discussed and compared with those of the corresponding complexes of Cr and analogous 1,4,7-triazacyclononane complexes. The single-crystal structures of the 1,3,5-tri-tert-butyl-1,3,5-triazacyclohexane adducts with Mo and W have been determined.

引用

页码：1145 / 1149

页数：5

共 24 条

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