Enantiopure arene dioxides:: chemoenzymatic synthesis and application in the production of trans-3,4-dihydrodiols

被引：25

作者：

Boyd, DR ^{[1
]}

Sharma, ND ^{[1
]}

O'Dowd, CR ^{[1
]}

Hempenstall, F ^{[1
]}

机构：

[1] Queens Univ Belfast, Sch Chem, Belfast BT9 5AG, Antrim, North Ireland

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 21期

关键词：

D O I：

10.1039/b006837n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Enantiopure syn- and anti-arene dioxides are synthesised from cis-dihydrodiol metabolites; anti-benzene dioxides are reduced to enantiopure trans-3,4-dihydrodiols while syn-benzene dioxides racemise thermally via 1,4-dioxocins.

引用

页码：2151 / 2152

页数：2

共 21 条

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