Structure of a precursor in the synthesis of low-spin iron(II) complexes of Schiff base ligands

被引：7

作者：

Alshehri, S

Burgess, J ^{[1
]}

Fawcett, J

Russell, DR

Shaker, AM

机构：

[1] Univ Leicester, Dept Chem, Leicester LE1 7RH, Leics, England

[2] King Saud Univ, Dept Chem, Riyadh 11451, Saudi Arabia

[3] S Valley Univ, Fac Sci, Dept Chem, Sohag, Egypt

来源：

TRANSITION METAL CHEMISTRY | 2000年 / 25卷 / 06期

关键词：

D O I：

10.1023/A:1007025706498

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Crystals obtained in the course of preparing the tris-Schiff base iron(II) complex from 2-acetylpyridine and benzylamine have been shown by an X-ray diffraction structure determination to contain an iron(II) complex cation containing two molecules of the target Schiff base and one molecule of 2-acetylpyridine coordinated to the metal. The mechanistic implications of this fact are discussed.

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页码：691 / 694

页数：4

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