Reactions of the unsaturated azides -: Part 15 -: Synthesis and reactions of the first cyclopentadienyl isonitriles

被引：13

作者：

Banert, K ^{[1
]}

Köhler, F ^{[1
]}

Meier, B ^{[1
]}

机构：

[1] Chemnitz Univ Technol, Inst Chem, D-09111 Chemnitz, Germany

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 19期

关键词：

azides; fulvenes; cyclopentadienes; isocyanides; Diels Alder reactions;

D O I：

10.1016/S0040-4039(03)00784-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

6-Azidofulvenes without a further substituent in the exocyclic position were transformed into new 1-isocyano- and 2-isocyanocyclopenta-1,3-dienes by photolysis in methanol. These novel functionalized cyclopentadienes are useful building blocks, e.g. as dienes in Diels-Alder reactions. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：3781 / 3783

页数：3

共 8 条

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[2] 2-F
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[4] SYNTHESIS OF PYRIDO[B]CYCLOBUTEN-5-ONE AND 1-AZAFULVENALLENE BY FLASH VACUUM PYROLYSIS OF 3-CHLOROFORMYL-2-METHYLPYRIDINE
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WU, CC
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[5] A SIMPLE SYNTHESIS OF SUBSTITUTED FULVENES FROM 6-FULVENYL P-TOLUENESULFONATES
HAFNER, K
BAUER, W
SCHULZ, G
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1968, 7 (10) : 806 - &
[6] HAFNER K, 1968, ANGEW CHEM, V88, P800
[7] Ivchenko NB, 2000, RUSS J ORG CHEM+, V36, P609
[8] RUCHARDT C, 1992, CHEM BER, V125, P525

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