Reactions of the unsaturated azides -: Part 15 -: Synthesis and reactions of the first cyclopentadienyl isonitriles

被引:13
作者
Banert, K [1 ]
Köhler, F [1 ]
Meier, B [1 ]
机构
[1] Chemnitz Univ Technol, Inst Chem, D-09111 Chemnitz, Germany
关键词
azides; fulvenes; cyclopentadienes; isocyanides; Diels Alder reactions;
D O I
10.1016/S0040-4039(03)00784-6
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
6-Azidofulvenes without a further substituent in the exocyclic position were transformed into new 1-isocyano- and 2-isocyanocyclopenta-1,3-dienes by photolysis in methanol. These novel functionalized cyclopentadienes are useful building blocks, e.g. as dienes in Diels-Alder reactions. (C) 2003 Elsevier Science Ltd. All rights reserved.
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页码:3781 / 3783
页数:3
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